Home Forums Hyperfine course ERP EPR on free atoms (2) First and second answer

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    Himanshu Sharma
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    First one :- if the energy is right amount it will change it’s orientation
    Second one :-
    1) Without hyperfine interaction
    △Eo= gμBBo=1×(5.78838 × 10-5)x2= 1.15767636 × 10-4 eV.
    1.1577x 10-4 eV
    2) With hyperfine term written as
    Hnf = A,mrm]
    The other a
    BUT when a transition has △m=+1 and a fixed nuclear
    projection my=±},the hyperfine contribution to the
    transition energy is
    △Enr=Am△my=A.my·1=±
    Numerically:
    • A/2=1.05082 ×10-7eV.
    Thus the two components of the transition are
    △E=△EO±=1.15767636×10-4eV±1.05082×10-7eV.

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